Philip R. Brooks


Publications


"Crossed-beam studies of electron transfer to oriented trichloronitromethane, CCl3NO2, molecules", Peter. W. Harland and Philip. R. Brooks, J. Chem. Phys. 132 (4), 044307 (2010)


"Electron Transfer Collisions with Oriented Trifluoroacetic Acid (CF3CO2H)", Philip R. Brooks, J. Phys. Chem. A 113 (52), 14296 (2009).


"Experimental evidence for the role of the π*CO orbital in electron transfer to gas phase acetic acid CH3CO2H: Effects of molecular orientation", Philip R. Brooks, J. Chem. Phys., 130, 151102 (2009)


“Steric Effects in Electron Transfer from Potassium to π-bonded Oriented Molecules CH3CN, CH3NC, and CCl3CN” Philip R. Brooks, Peter W. Harland, Sean A. Harris, Terry Kennair, Crystal Redden, and Jack F. Tate, J. Am. Chem. Soc., 2007 129 15572-80


 “Steric asymmetry in electron transfer from potassium atoms to oriented nitromethane (CH3NO2) molecules”, Philip R. Brooks, Peter W. Harland, and Crystal E. Redden, J. Phys. Chem. A 2006, 110 4697-4701


“Electron Transfer from Sodium to Oriented Nitromethane, CH3NO2:  Probing the Spatial Extent of Unoccupied Orbitals”, Philip R. Brooks, Peter W. Harland, and Crystal E. Redden, J. Am. Chem Soc. 2006, 128 4773-4778


"Threshold Behavior in Electron-Transfer Collisions between Rubidium Atoms and C3F5Cl or C3F5I Molecules", Beike Jia, Sean Harris, Larry L. Lewis, Jiping Zhan, and Philip R. Brooks, J. Phys. Chem., 109(41), 9213-9219, (2005)


"Dramatic steric behavior in electron transfer from various donors to CF3Br", Peter W. Harland and Philip R. Brooks, J. Am. Chem. Soc.  2003  125 (43) 13191-13197


"Evidence for Orbital-Specific Electron Transfer to Oriented Haloform Molecules", Beike Jia, Jonathan Laib, R. F. M. Lobo, and Philip R. Brooks, J. Am. Chem. Soc.  2002; 124(46); 13896-13902


“Frontside Vs Backside Reactivity in Electron Transfer to Oriented tert Butyl Bromide and Methyl Bromide , Philip R. Brooks & Sean A. Harris , J. Chem. Phys 117, 4220-4232, (2002)


 “Electron Transfer to Oriented Molecules:  Surprising Steric Effect in t-Butyl Bromide”, Sean A. Harris & Philip R. Brooks, J. Chem. Phys.  114, 10569-72  (2001)


“Electron Transfer Collisions with Spatially Oriented CH3CN”, Sean A. Harris, Peter W. Harland & Philip R. Brooks, Phys. Chem. Chem. Phys. 2, 787-791 (2000)


“Electron Transfer to SF6 and Oriented CH3Br”, Sean A. Harris, Susan D. Wiediger, & Philip R. Brooks, J. Phys. Chem. A 1999, 103, 10035-10041


“Spatial deorientation of upper Stark state selected beams of CH3F, CH3Cl, CH3Br and CH3I in field free space”, Peter W. Harland, Wan-Ping Hu, Claire Vallance, and Philip R. Brooks, Phys Rev A  60, 3138-43 (1999)


"Characterization of Oriented Molecule Beams by Radio Frequency Spectroscopy", Susan D. Wiediger, Peter W. Harland , Judson R. Holt,  and Philip R. Brooks, J. Phys. Chem. A 1998, 102, 1112-1118


"The Role of Fine-structure States in a Chemical Reaction:  Na*+ KBr → NaBr + K*  Lawrence L. Lewis, Philip R. Brooks, Robert F. Curl, and Bruce R. Johnson, J.Phys.Chem., Kinsey issue, 100 8008-8010 (1996)


"Effect of Molecular Orientation on Electron Transfer and Electron Impact Ionization", P. R. Brooks & P. W. Harland, Advances in Gas Phase Ion Chemistry, N. G. Adams & L. M. Babcock, eds, JAI Press Vol 2, 1-39 (1996)


 "Orientation Effects in Electron Transfer Collisions", P. R. Brooks, International Reviews in Physical Chemistry  14 327-354 (1995 )


"Threshold Effects in Electron Transfer to Oriented Molecules", G. Xing, T. Kasai & P. R. Brooks, J. Am. Chem. Soc.   117 2581-2589  (1995)


"Evidence for Preferential Electron Transfer to the Br end of Oriented CF3Br", G. Xing, T. Kasai & P. R. Brooks, J. Am. Chem. Soc., 116 7421-22 (1994)


"Probing Chemical Reaction:  Evidence for Exploration of an Excited Potential Energy Surface at Thermal Energies", M. D. Barnes, P. R. Brooks, R. F. Curl, & B. R. Johnson, Science 261, 1434-1436 (1993)


 "Molecular Frame Coordinates and the Analysis of Scattering from Oriented Molecules", P. R. Brooks,   J. Phys. Chem. 97, 2153 (1993)


"Photoexcitation spectra of transition region species in reactions of potassium with sodium halides", M. D. Barnes, P. R. Brooks, R. F. Curl, P. W. Harland & B. R. Johnson, J. Chem. Phys. 96, 3559 (1992)


 "Collision dynamics of alkali metal atoms with oriented symmetric top molecules", P. R. Brooks, P. W. Harland, L. F. Phillips, & H. S. Carman, Jr., J. Phys. Chem., 96, 1557   (1992)


  "Effects of Molecular Orientation on Electron Transfer Collisions", P. W. Harland, H. S. Carman, Jr., L. F. Phillips & P. R. Brooks J. Phys. Chem.,J. Phys. Chem., 95, 8137 (1991)


 "Observation of Structure in Transition State Spectra of the Bimolecular Reactions K + XNa → KX + Na (X=Br,Cl)", M. D. Barnes, P. R. Brooks, R. F. Curl, Jr., and P. W. Harland J. Chem. Phys., 94, 5245 (1991


"Electron Transfer to Oriented Molecules:  K + CF3I and K +CH3I," P.W. Harland, H.S. Carman, Jr., L.F. Phillips, and P.R. Brooks, J. Chem. Phys., 93, 1089 (1990)


"Effect of Molecular Orientation on Electron Transfer," P. W. Harland, H. S. Carman, Jr., L. F. Phillips, and P. R. Brooks, J. Chem. Phys., 90, 5201 (1989)


"Spectroscopy of Transition Region Species," P. R. Brooks, Chem. Rev., 88, 407 (1988).


"Observation of the Laser-Assisted Reaction K + NaCl + hν → Na* + KCl Using K Atoms Selected by a Hexapole Magnetic Field," S. K. Kaesdorf, P. R. Brooks, R. F. Curl, J. H. Spence  and S. J. Ulvick, Phys. Rev., 34A, 4418 (1986).


"Photoexcitation of Reaction Complexes in the Reaction K + NaCl → KCl + Na," T. C. Maguire, P. R. Brooks, R. F. Curl, J. H. Spence and S. J. Ulvick, J.  Chem. Phys., 85, 844 (1986).


"Reaction of K Atoms with Oriented CF3Br," H. S. Carman, P. W. Harland and P. R. Brooks, J. Phys. Chem., 90, 944 (1986).


"Photoexcitation of the NaKCl Reaction Complex," Tom C. Maguire, Philip R. Brooks and R. F. Curl, Jr., Phys. Rev. Lett., 50, 1918 (1983).


""Experimental Observations Regarding Transition States," Philip R. Brooks, R. F. Curl and T. C. Maguire, Ber. Bunsenges, f. Phys. Chem., 86, 401 (1982)


"Reaction of Magnetically-State Selected NO with O3: Effect of Fine Structure States and Rotational States on Reactivity," Scott L. Anderson, Philip R. Brooks, James D. Fite and On Van Nguyen, J. Chem. Phys., 72, 6512 (1980).


"Chemiluminescent Reaction Channel Opened by Photon Absorption During Collision," Peter Hering, Philip R. Brooks, R. F. Curl, Jr., Richard S. Judson and R. S. Lowe, Phys. Rev. Lett., 44, 687 (1980).


"Molecular Beam Reaction of K Atoms with Sideways Oriented CF3I," Philip R. Brooks, John S. McKillop and H. Gary Pippin, Chem. Phys. Lett., 66, 144 (1979).


"Molecular Beam Reaction of K with HCl: Effect of Rotational State of HCl," Helmut H. Dispert, Michael W. Geis and Philip R. Brooks, J. Chem. Phys., 70, 5317 (1979).


"Total Cross Section Measurements of the Reaction K = HCl → KCl + H as a Function of Translation Energy (2-20 kcal/mole)," M. Geis, H. Dispert, T. L. Budzynski  and P. R. Brooks, ACS Symp Ser., 56, 103 (1977).


"Products of the Gas Phase K + CF3I Reactions," J. Hardee and P. R. Brooks, J. Phys. Chem., 81, 1031 (1977).


"Reactions of Oriented Molecules," Philip R. Brooks, Science, 193, 11 (1976).


"Translational Excitation of the Molecular Beam Reaction K + HCl → KCl + H," J. Gary Pruett, Frederick R. Grabiner and Philip R. Brooks, J. Chem. Phys., 63, 1173 (1975).


"Steric Hindrance in Potassium Atom-Oriented Molecule Reactions.  Methyl Iodide and tert-Butyl Iodide," George Marcelin and Philip R. Brooks, J. Am. Chem. Soc., 97, 1710 (1975).


"Molecular Beam Reaction of K with HCl:  Effect of Translational Excitation of Reagents," J. Gary Pruett, Frederick R. Grabiner and Philip R. Brooks, J. Chem. Phys., 60, 3335 (1974).


"Steric Hindrance in Molecular Beam Reactions," George Marcelin and Philip R. Brooks, J. Am. Chem. Soc., 95, 7885 (1973).


"Scattering of K Atoms from Oriented CF3I.  Reaction at both 'Ends'," Philip R. Brooks, Faraday Disc. Chem. Soc., 55, 299 (1973).


"Metastable Hydrogen Molecules. III. Hyperfine Structure of Orthohydrogen," P. R. Brooks, W. Lichten and R. Reno, Phys. Rev. A, 4, 2217 (1971)


"Molecular Beam Reaction of K with HCl:  Effect of Vibrational Excitation of HCl," Truman J. Odiorne, Philip R. Brooks and Jerome V. V. Kasper, J.  Chem. Phys., 55, 1980 (1971)


"Focusing and Orienting Asymmetric-Top Molecules in Molecular Beams," Eugene M. Jones and Philip R. Brooks, J. Chem. Phys., 53, 55 (1970).


"Molecular Beam Reaction of K with HCl: Evidence for an Activation Energy," Truman J. Odiorne and Philip R. Brooks, J. Chem. Phys., 51, 4676 (1969)


"Orienting Polar Molecules in Molecular Beams.  Symmetric Tops," Philip R. Brooks, Eugene M. Jones and Ken Smith, J. Chem. Phys., 51, 3073 (1969)


"Molecular Beam Reaction of K with Oriented CF3I.  Evidence for Harpooning?," Philip R. Brooks, J. Chem. Phys., 50, 5031 (1969).


Reactive Scattering of K Atoms from Oriented CH3I Molecules," Philip R. Brooks and Eugene M. Jones, J. Chem. Phys., 45, 3449 (1966)


"Kingdon Cage as a Molecular Beam Detector," Philip R. Brooks and D. R. Herschbach, Rev. Sci. Instr., 35, 1528 (1964).


"Mercury(II) Complexes of Imidazole and Histidine," Philip R. Brooks and Norman Davidson, J. Am. Chem. Soc., 82, 2118 (1960)