![]() |
![]() |
![]() |
Home Publications |
Are Chemical Reactions dependent on reagent orientation? Indirect Evidence: yes "Common Sense" (dates back to ancient Greece) "Chemical Intuition" (more modern version of above) Molecular Structure Electron & X-ray diffraction Spectroscopy Reactivity Walden inversion Kinetic steric factors Direct Evidence: YES! We orient dipolar molecules in molecular beams and compare the reactivity at the positive end and the negative end. (more coming--this research supported by the NSF) |