Thermodynamics of Electrolytes

Electrolytes play important roles in science and industry. However, the complete thermodynamic description of these systems is still an open question. Current experimental and theoretical studies are focused on critical properties of ionic fluids where controversial results exist. We are developing Debye-Huckel-based theories for lattice models of electrolytes. Our theories are focusing on the effects of size- and charge asymmetry of charged particles on macroscopic thermodynamic properties. We are checking our theoretical predictions with extensive computer simulations. In this area our collaborator is Prof. Panagiotopoulos from Princeton University.